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Efficient and selective palladium-catalyzed direct oxidative esterification of benzylic alcohols under aerobic conditions
Tetrahedron ( IF 2.1 ) Pub Date : 2017-11-13 , DOI: 10.1016/j.tet.2017.11.025
Yongke Hu , Bindong Li

A highly efficient palladium-catalyzed approach for the direct oxidative esterification of benzylic alcohols with methanol and long-chain aliphatic alcohols under mild conditions has been achieved. This practical catalyst system exhibits a broad substrate scope and good functional group tolerance. Catalytic amount of Bi(OTf)3 is used as co-catalyst to improve the activity and selectivity of the reactions. A variety of esters are obtained in yields of 43–96%.



中文翻译:

在好氧条件下高效选择性地催化钯催化苄醇的直接氧化酯化反应

已经实现了在温和条件下用甲醇和长链脂族醇将苄醇直接氧化酯化的高效钯催化方法。这种实用的催化剂体系具有广泛的底物范围和良好的官能团耐受性。催化量的Bi(OTf)3用作助催化剂,以提高反应的活性和选择性。获得了多种酯,产率为43–96%。

更新日期:2017-11-13
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