Emerging crystalline porous materials as a multifunctional platform for electrochemical energy storage,Chemical Society Reviews

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Emerging crystalline porous materials as a multifunctional platform for electrochemical energy storage
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2017-09-28 00:00:00 , DOI: 10.1039/c7cs00283a
Junwen Zhou _{1,

2,

3,

4,

5} , Bo Wang _{1,

2,

3,

4,

5}

Affiliation

Metal–organic frameworks (MOFs) and covalent-organic frameworks (COFs) are two emerging and explosively growing families of crystalline porous materials (CPMs). These robust frameworks are characterized by their extraordinary porosity, tremendous structural diversity, and versatile functional tunability with precision at the molecular level. In this review, we present recent milestones of MOFs and COFs in the fields of batteries and supercapacitors, two important technologies in electrochemical energy storage (EES), and highlight the functions that a CPM can offer in EES devices, including the storage of electrochemical energy, stabilization of electrode materials, pathways for charge transport, manipulation on mass transport, and promotion of electrochemical reactions. Key requirements for each function are discussed, with future directions provided for further development.

中文翻译：

新兴的晶体多孔材料作为电化学能量存储的多功能平台

金属有机框架（MOF）和共价有机框架（COF）是两个新兴且爆炸性增长的晶体多孔材料（CPM）系列。这些坚固的框架的特点是具有非凡的孔隙度，巨大的结构多样性以及在分子水平上具有精确度的多功能功能可调性。在本文中，我们介绍了电池和超级电容器领域中MOF和COF的最新里程碑，这是电化学能量存储（EES）的两项重要技术，并着重介绍了CPM在EES设备中可以提供的功能，包括电化学能量的存储，电极材料的稳定化，电荷传输的途径，质量传输的操纵以及电化学反应的促进。讨论了每个功能的关键要求，

更新日期：2017-11-13

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