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Palladium-Catalyzed Copper-Promoted Hiyama-Type Carbon–­Carbon Cross-Coupling Reactions of Dihetaryl Disulfides as ­Electrophiles
Synlett ( IF 1.7 ) Pub Date : 2017-10-26 , DOI: 10.1055/s-0036-1589116
Zheng-Jun Quan 1 , Xi-Cun Wang 1 , Ming-Xia Liu 1 , Hai-Peng Gong 2
Affiliation  

Dihetaryl disulfides were used as electrophiles in a palladium-catalyzed carbon–carbon cross-coupling reaction with arylsilanes to ­realize a Hiyama-type reaction. This unique transformation shows high reactivity, excellent functional-group tolerance, and mild reaction conditions, making it an attractive alternative to conventional cross-coupling approaches for carbon−carbon bond construction.

中文翻译:

钯催化铜促进的二杂芳基二硫化物作为亲电试剂的Hiyama型碳-碳交叉偶联反应

二杂芳基二硫化物在钯催化的碳-碳交叉偶联反应中与芳基硅烷用作亲电试剂以实现 Hiyama 型反应。这种独特的转变显示出高反应性、优异的官能团耐受性和温和的反应条件,使其成为传统的碳-碳键构建交叉偶联方法的有吸引力的替代方法。
更新日期:2017-10-26
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