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Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway
Synlett ( IF 1.7 ) Pub Date : 2017-10-23 , DOI: 10.1055/s-0036-1591495
Magnus Rueping 1, 2 , Shao-Chi Lee 1 , Lin Guo 1 , Huifeng Yue 1 , Hsuan-Hung Liao 1
Affiliation  

A nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon–heteroatom bond formations in a straightforward and mild fashion.

中文翻译:

通过脱酰胺反应途径对芳酰胺进行镍催化脱羰甲硅烷基化、硼酸化和胺化

已开发出镍催化的脱羰基硅烷化、硼化和酰胺胺化。这种新方法允许酰胺直接相互转化为芳基硅烷、芳基硼酸酯和芳基胺,并能够以简单和温和的方式形成碳-杂原子键的简便途径。
更新日期:2017-10-23
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