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Preparation of Aryl(dicyclohexyl)phosphines by C–P Bond-Forming Cross-Coupling in Water Catalyzed by an Amphiphilic-Resin-Supported Palladium Complex
Synlett ( IF 1.7 ) Pub Date : 2017-10-16 , DOI: 10.1055/s-0036-1590926 Yoshinori Hirai 1 , Yasuhiro Uozumi 1
Synlett ( IF 1.7 ) Pub Date : 2017-10-16 , DOI: 10.1055/s-0036-1590926 Yoshinori Hirai 1 , Yasuhiro Uozumi 1
Affiliation
Aryl(dicyclohexyl)phosphines were prepared by a catalytic C–P bond-forming cross-coupling reaction of haloarenes with dicyclohexylphosphine under heterogeneous conditions in water containing an immobilized palladium complex coordinated to an amphiphilic polystyrene–poly(ethylene glycol) resin supported di(tert-butyl)phosphine ligand.
中文翻译:
两亲树脂负载钯配合物催化水中C-P键形成交叉偶联制备芳基(二环己基)膦
芳基(二环己基)膦是通过卤代芳烃与二环己基膦在非均相条件下通过催化 C-P 键形成交叉偶联反应制备的,水中含有与两亲性聚苯乙烯-聚(乙二醇)树脂配位的固定化钯配合物。 -丁基)膦配体。
更新日期:2017-10-16
中文翻译:
两亲树脂负载钯配合物催化水中C-P键形成交叉偶联制备芳基(二环己基)膦
芳基(二环己基)膦是通过卤代芳烃与二环己基膦在非均相条件下通过催化 C-P 键形成交叉偶联反应制备的,水中含有与两亲性聚苯乙烯-聚(乙二醇)树脂配位的固定化钯配合物。 -丁基)膦配体。