Chemical Physics ( IF 2.0 ) Pub Date : 2017-11-08 , DOI: 10.1016/j.chemphys.2017.11.001 Martina Zámečníková , Pavel Soldán
Radiative lifetimes of the ro-vibrational bound states of HeLi+(b3∑+) are calculated quantum-mechanically when both bound-bound and bound-free processes are taken into account. The calculations are restricted to the initial states with low rotational quantum numbers. For the rotationless molecular ion, the shortest lifetime is 1.30×10-6s of the ground vibrational state. With increasing vibration excitations the radiative lifetimes slightly increase, but keep below 10-5s for next 17 vibrational states, then they start to increase more rapidly up to 2.41×10-2s for the highest vibrational state. The radiative lifetimes also tend to slightly prolong with increasing rotation excitations but stay on the same magnitude for the low rotational quantum numbers.
中文翻译:
HeLi +(b 3 ∑ +的辐射衰减)
HeLi +的振动振动束缚态的辐射寿命(b 3 ∑ +当同时考虑到有界和无界过程时,将以量子力学方式计算)。该计算仅限于具有低旋转量子数的初始状态。对于不旋转的分子离子,最短寿命为1.30×10 -6 s的振动状态。随着振动激发的增加,辐射寿命略有增加,但保持在10 -5 s以下在接下来的17个振动状态下,它们开始更快地增加,直到2.41×10 -2 s以获得最高的振动状态。辐射寿命也随着旋转激发的增加而略微延长,但对于低旋转量子数则保持相同的幅度。