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Radiative decay of HeLi+(b3∑+∑+)
Chemical Physics ( IF 2.0 ) Pub Date : 2017-11-08 , DOI: 10.1016/j.chemphys.2017.11.001
Martina Zámečníková , Pavel Soldán

Radiative lifetimes of the ro-vibrational bound states of HeLi+HeLi+(b3+b3+) are calculated quantum-mechanically when both bound-bound and bound-free processes are taken into account. The calculations are restricted to the initial states with low rotational quantum numbers. For the rotationless molecular ion, the shortest lifetime is 1.30×10-6s1.30×10-6s of the ground vibrational state. With increasing vibration excitations the radiative lifetimes slightly increase, but keep below 10-5s10-5s for next 17 vibrational states, then they start to increase more rapidly up to 2.41×10-2s2.41×10-2s for the highest vibrational state. The radiative lifetimes also tend to slightly prolong with increasing rotation excitations but stay on the same magnitude for the low rotational quantum numbers.



中文翻译:

HeLi +b 3 +的辐射衰减+

HeLi +的振动振动束缚态的辐射寿命合力+b 3+b3+当同时考虑到有界和无界过程时,将以量子力学方式计算)。该计算仅限于具有低旋转量子数的初始状态。对于不旋转的分子离子,最短寿命为1.30×10 -6 s1.30×10--6s的振动状态。随着振动激发的增加,辐射寿命略有增加,但保持在10 -5 s以下10--5s在接下来的17个振动状态下,它们开始更快地增加,直到2.41×10 -2 s2.41×10--2个s以获得最高的振动状态。辐射寿命也随着旋转激发的增加而略微延长,但对于低旋转量子数则保持相同的幅度。

更新日期:2017-11-10
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