A Large Family of Halogen-Bonded Cocrystals Involving Metal–Organic Building Blocks with Open Coordination Sites,Crystal Growth & Design

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A Large Family of Halogen-Bonded Cocrystals Involving Metal–Organic Building Blocks with Open Coordination Sites
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2017-11-07 00:00:00 , DOI: 10.1021/acs.cgd.7b01325
Vinko Nemec ₁ , Luka Fotović ₁ , Tomislav Friščić ₂ , Dominik Cinčić ₁

Affiliation

We demonstrate a design for halogen-bonded metal–organic cocrystals involving coordinatively unsaturated square-planar Cu(II) and Ni(II) centers, by utilizing a Schiff base ligand whose pendant acetyl group enables halogen bonding. The robustness of this design is evident by the assembly of a large family of eight cocrystals based on zero-, one-, and two-dimensional halogen bonded architectures involving mono- or ditopic halogen bond donors based on iodine or bromine.

中文翻译：

涉及金属-有机结构单元且具有开放配位位点的大量卤素键合共晶体

我们通过利用席夫碱配体（其悬垂的乙酰基可实现卤素键合）证明了涉及键合不饱和方平面Cu（II）和Ni（II）中心的卤素键合金属-有机共晶体的设计。这种设计的鲁棒性是通过组装基于零维，一维和二维卤素键结构的八个共晶体的大家族而实现的，这些晶体涉及基于碘或溴的单或双位卤素键供体。

更新日期：2017-11-08

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