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Development of Pyrene Derivatives as Promising n-Type Semiconductors: Synthesis, Structural and Spectral Properties
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2017-11-08 09:32:25 , DOI: 10.1002/ajoc.201700441
Minglun Liu 1 , Xiaojie Gong 1 , Chaoyue Zheng 1 , Deqing Gao 1
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Just my type: A series of pyrene derivatives were synthesized. In contrast with 1,6-position substitution, 1,8-position substitution had smaller dihedral angles and facilitated large conjugation and intermolecular stacking. The dicyanovinylene substitution strengthened the coplanarity and enhanced π-conjugated systems. The lowest unoccupied molecular orbital (LUMO) energy level was located deeply and they may be promising candidates of n-type semiconductors.

中文翻译:

Pro衍生物作为有前途的n型半导体的发展:合成,结构和光谱性质。

只是我的类型:合成了一系列of衍生物。与1,6-位取代相反,1,8-位取代具有较小的二面角,并促进了大的共轭和分子间堆积。双氰基亚乙烯基取代增强了共面性并增强了π共轭体系。最低的未占据分子轨道(LUMO)能级位于很深的地方,它们可能是n型半导体的有希望的候选者。
更新日期:2017-11-08
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