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Carbon nanotubes covalent combined with graphitic carbon nitride for photocatalytic hydrogen peroxide production under visible light
Applied Catalysis B: Environment and Energy ( IF 20.2 ) Pub Date : 2017-11-04 , DOI: 10.1016/j.apcatb.2017.11.005
Shen Zhao , Tao Guo , Xia Li , Tongguang Xu , Bo Yang , Xu Zhao

The carbon nanotubes (CNTs) have been combined with graphitic carbon nitride (g-C3N4) through the amidation reaction. The hybrid catalyst of g-C3N4-CNTs with well-defined and stable structure exhibits efficient catalytic performance (32.6 μmol h−1) for photocatalytic H2O2 production in the presence of formic acid under visible light. The value of electron transfer during the oxygen reduction reaction (ORR) process obtained from the Koutecky-Levich plot for g-C3N4-CNTs (n = 1.96) is higher than that for g-C3N4 (n = 1.29), suggesting that the CNTs covalent combined with g-C3N4 can promote the electrons generation. The p-benzoquinone (PBQ) scavenger experiments, the electron spin resonance (ESR) signal and quantitative experiment of O2 results reveal that the negative shifts of the conduction band (CB) level from g-C3N4 to g-C3N4-CNTs can enhance the single-electron reduction of O2 to O2 and further promote the sequential two-step single-electron O2 reduction reaction to H2O2.



中文翻译:

碳纳米管共价结合石墨氮化碳在可见光下光催化生产过氧化氢

碳纳米管(CNT )通过酰胺化反应与石墨碳氮化物(gC 3 N 4)结合。具有明确和稳定结构的gC 3 N 4 -CNTs杂化催化剂在甲酸存在下于可见光下表现出有效的催化性能(32.6μmolh -1),可用于光催化H 2 O 2的生产。从Koutecky-Levich图获得的gC 3 N 4 -CNTs(n = 1.96)的氧还原反应(ORR)过程中的电子转移值高于gC 3 N 4的电子转移值(n = 1.29),表明与gC 3 N 4共价结合的CNT可以促进电子的产生。的p苯醌(PBQ)清除剂的实验中,电子自旋共振(ESR)信号和定量试验的ö 2 -结果表明,该导带(CB)水平的负偏移从GC 3 Ñ 4至GC 3 Ñ 4 - CNT可以提高的O的单电子还原2ö 2 - ,进一步推动连续两步单电子ö 2还原反应至H 2 ö2

更新日期:2017-11-04
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