A copper-catalyzed, enantioselective method for the borylallylation of vinyl arenes is reported. The reaction produces enantioenriched and functionalized organoboron compounds by sequentially incorporating boryl and allyl groups onto the C═C bond of vinyl arenes. Copper-catalyzed borylative coupling of vinyl arenes with allyl phosphates successfully proceeds in a regio- and enantioselective manner in the absence of a palladium cocatalyst.

中文翻译：

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铜催化乙烯基芳烃的不对称硼烷基化

报道了铜催化的乙烯基芳烃的硼烷基化的对映选择性方法。该反应通过将硼烷基和烯丙基顺序地结合到乙烯基芳烃的C═C键上而产生对映体富集和官能化的有机硼化合物。在不存在钯助催化剂的情况下，铜芳烃与烯丙基磷酸酯的铜催化的硼烷基化偶联成功地以区域选择性和对映选择性的方式进行。