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Me3P-catalyzed addition of hydrogen phosphoryl compounds P(O)H to electron-deficient alkenes: 1 to 1 vs 1 to 2 adducts
Tetrahedron ( IF 2.1 ) Pub Date : 2017-10-31 , DOI: 10.1016/j.tet.2017.10.070
Tian-Zeng Huang , Tieqiao Chen , Yuta Saga , Li-Biao Han

Trimethyl phosphine was used as an efficient catalyst for the addition of P(O)-H compounds to electron-deficient alkenes. The addition reactions were generally conducted using a catalytic amount of Me3P under mild reaction conditions. Both 1 to 1 and 1 to 2 adducts were obtained.



中文翻译:

Me 3 P催化的氢磷酰基化合物P(O)H向缺电子烯烃的加成:1:11-2加合物

三甲基膦被用作将P(O)-H化合物加成至缺电子烯烃的有效催化剂。通常在温和的反应条件下使用催化量的Me 3 P进行加成反应。获得了1对1和1对2个加合物。

更新日期:2017-10-31
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