当前位置: X-MOL 学术Mater. Chem. Front. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Hybridization of metal–organic frameworks and task-specific ionic liquids: fundamentals and challenges
Materials Chemistry Frontiers ( IF 6.0 ) Pub Date : 2017-10-20 00:00:00 , DOI: 10.1039/c7qm00416h
Qun-xing Luo 1, 2, 3, 4, 5 , Bo-wen An 6, 7, 8, 9, 10 , Min Ji 6, 7, 8, 9, 10 , Jie Zhang 2, 11, 12, 13, 14
Affiliation  

Metal–organic frameworks (MOFs) and task-specific ionic liquids (TSILs) have been active as a high-profile class of versatile materials. However, there was no relatively close intersection between MOFs and TSILs until the concept of hybridization of MOFs and TSILs was proposed in the most recent years. At present, it has been well witnessed that the development of MOF and TSIL hybrid materials (MTHMs) is attracting significant attention. In this regard, it is high time to address the recent advances made in the fast-growing field of MTHMs and provide a critical assessment of this subject matter. In this review, as an originator of MTHMs, we have presented a logical and easy-to-follow story about the hybridization of MOFs and TSILs: from their origins, to the motivation behind hybridization, to a strategy to carry out the hybridization, and finally to the consequences of hybridization based on a few illustrative examples. Finally, the specific bottlenecks, challenges, and outlooks towards this subject matter have been proposed according to the state-of-the-art progress as well as our first-hand experiences and personal perspectives. Hopefully, the knowledge and learning points gained from this review will deepen the understanding of MTHMs and appeal to more multidisciplinary communities coming forward with their valuable contributions in the coming decades.

中文翻译:

金属有机框架与特定任务的离子液体的杂交:基本原理和挑战

金属有机框架(MOF)和特定任务的离子液体(TSIL)一直是一类引人注目的多功能材料。但是,直到最近几年提出了MOF和TSIL杂交的概念之前,MOF和TSIL之间并没有相对紧密的交集。目前,众所周知,MOF和TSIL混合材料(MTHMs)的开发引起了广泛的关注。在这方面,现在该是应对在快速增长的MTHM领域取得的最新进展并对该主题进行严格评估的时候了。在这篇评论中,作为MTHM的发起者,我们介绍了一个关于MOF和TSIL杂交的逻辑且易于理解的故事:从它们的起源到杂交背后的动机,再到进行杂交的策略,最后基于几个说明性例子来说明杂交的后果。最后,根据最新进展以及我们的第一手经验和个人观点,提出了针对该主题的特定瓶颈,挑战和前景。希望从这次审查中获得的知识和学习点将加深对MTHM的理解,并吸引更多的跨学科社区在未来几十年中做出宝贵贡献。
更新日期:2017-11-01
down
wechat
bug