Recent progress in conversion reaction metal oxide anodes for Li-ion batteries,Materials Chemistry Frontiers

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Recent progress in conversion reaction metal oxide anodes for Li-ion batteries
Materials Chemistry Frontiers ( IF 6.0 ) Pub Date : 2017-06-26 00:00:00 , DOI: 10.1039/c7qm00175d
Kangzhe Cao _{1,

2,

3,

4,

5} , Ting Jin _{1,

2,

3,

4,

5} , Li Yang _{1,

2,

3,

4,

5} , Lifang Jiao _{1,

2,

3,

4,

5}

Affiliation

Transition metal oxides (TMOs) based on conversion reactions are attractive candidate anode materials for lithium-ion batteries (LIBs) because of their high theoretical capacity and safety characteristics. In this review, we have summarized recent progress in the rational design and efficient synthesis of TMOs with controllable morphologies, compositions, and micro-/nanostructures, along with their Li storage behaviors. Single metal oxides of manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), ruthenium (Ru), chromium (Cr), molybdenum (Mo), and tungsten (W) and their common binary metal oxides have been discussed in this review. Finally, the less well-known merits of conversion reactions are put forward, and the design of metal oxide electrodes making full use of these merits has been proposed.

中文翻译：

锂离子电池转化反应金属氧化物阳极的最新进展

基于转化反应的过渡金属氧化物（TMOs）具有很高的理论容量和安全特性，是锂离子电池（LIB）的有吸引力的候选阳极材料。在这篇综述中，我们总结了合理设计和有效合成TMO的最新进展，这些TMO具有可控的形态，组成和微/纳米结构，以及它们的Li储存行为。锰（Mn），铁（Fe），钴（Co），镍（Ni），铜（Cu），钌（Ru），铬（Cr），钼（Mo）和钨（W）的单一金属氧化物和本综述讨论了它们常见的二元金属氧化物。最后，提出了鲜为人知的转化反应的优点，并提出了充分利用这些优点的金属氧化物电极的设计。

更新日期：2017-10-26

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