Molecular Iodine-Promoted Transimination for the Synthesis of 6-Phenylpyrido[2′,1′:2,3]imidazo[4,5-c]quinoline and 6-(Pyridin-2-yl)pyrido[2′,1′:2,3]imidazo[4,5-c]quinolines,Asian Journal of Organic Chemistry

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Molecular Iodine-Promoted Transimination for the Synthesis of 6-Phenylpyrido[2′,1′:2,3]imidazo[4,5-c]quinoline and 6-(Pyridin-2-yl)pyrido[2′,1′:2,3]imidazo[4,5-c]quinolines
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2017-10-25 10:12:11 , DOI: 10.1002/ajoc.201700357
Satish Sunkari ₁ , Siddiq Pasha Shaik ₁ , Namballa Hari Krishna _{1,

2} , Ayanampudi Venkata Subba Rao _{1,

3} , Bheeshma Geetanjali Kodiripaka ₁ , Abdullah Alarifi ₄ , Ahmed Kamal _{1,

2,

4}

Affiliation

I-2 can-do system: An efficient I₂-mediated approach for the synthesis of 6-phenylpyrido[2′,1′:2,3]imidazo[4,5-c]quinoline heterocyclic skeletons has been achieved from the reaction of benzylamines and 2-(imidazo[1,2-a]pyridin-2-yl)anilines. This one-pot protocol proceeds through an oxidation/transimination/cyclization/aromatization reaction sequence under metal-free conditions to result in the formation of N−C and C−C bonds.

中文翻译：

分子碘促进的氨基转移反应合成6-苯基吡啶并[2'，1'：2,3]咪唑并[4,5-c]喹啉和6-（吡啶-2-基）吡啶并[2'，1'： 2,3]咪唑并[4,5-c]喹啉

I-2 Can-do系统：从反应中获得了一种高效的I ₂介导的合成6-苯基吡啶并[2'，1'：2,3]咪唑并[4,5 -c ]喹啉杂环骨架的方法苄胺和2-（咪唑并[1,2 - a ]吡啶-2-基）苯胺。该一锅法实验流程是在无金属的条件下进行氧化/氨化/环化/芳构化反应序列，从而导致形成N-C和C-C键。

更新日期：2017-10-26

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