Self-assembly of polyhedral metal–organic framework particles into three-dimensional ordered superstructures

Nature Chemistry, Published online: 23 October 2017; doi:10.1038/nchem.2875

Colloidal particles of metal–organic frameworks (ZIF-8 and UiO-66) with different polyhedral shapes can self-assemble into well-ordered, porous three-dimensional superstructures. These superstructures function as photonic crystals, with a photonic band gap that depends on the size of the MOF particles and shifts upon the sorption of guests within their pores.

中文翻译：

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多面体金属-有机骨架颗粒的自组装成三维有序超结构

多面体金属-有机骨架颗粒的自组装成三维有序超结构

《自然化学》，在线发布：2017年10月23日; doi：10.1038 / nchem.2875

具有不同多面体形状的金属-有机骨架（ZIF-8和UiO-66）的胶体颗粒可以自组装成有序的多孔三维三维结构。这些超结构起到光子晶体的作用，其光子带隙取决于MOF粒子的大小，并取决于其孔中客体的吸附。