Two series of novel polycatenar dyes consisting of a triazole azobenzene core were synthesized efficiently by copper-catalyzed azide-alkyne cycloaddition (CuAAC) reaction. These compounds can self-assemble into SmC and Col_hex/p6mm liquid-crystalline phases, and form multistimuli responsive organogels. Bicontinuous cubic phase (Cub_V) could be induced in the binary system of a bicatenar compound with SmC phase and a hexacatenar compound with Col_hex/p6mm phase. Photophysical investigation indicates that these compounds have reversible photoresponsive properties in solution, liquid-crystalline and gel states. They can also act as chemosensors of Fe³⁺ and sodium dithionite with high selectivity.

通过铜催化的叠氮化物-炔烃环加成反应（CuAAC）有效地合成了由三唑偶氮苯核组成的两类新型聚对苯二酚染料。这些化合物可以自组装成SmC和Col _hex / p 6 mm液晶相，并形成多刺激响应性有机凝胶。双连续立方相（Cub _V）可以在具有SmC相的双catenar化合物和具有Col _hex / p 6 mm相的hexacatenar化合物的二元体系中诱发。光物理研究表明，这些化合物在溶液状态，液晶状态和凝胶状态下具有可逆的光响应特性。它们还可以充当Fe的化学传感器³⁺和连二亚硫酸钠具有高选择性。