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Enhanced Relative Stability of Metallabenzenes versus Metallocenes upon Ring Perfluorination: Nickel, Palladium, and Platinum Systems
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-10-16 08:20:38 , DOI: 10.1002/ejic.201700810
Jing Li 1 , Guoliang Li 1, 2, 3 , Yaoming Xie 3 , R. Bruce King 1, 3 , Henry F. Schaefer 3
Affiliation  

Perfluorination of one η5-C5H5 ring in the MC10H10 system (M = Ni, Pd, Pt) to give an MC10H5F5 system greatly destabilizes structures containing a perfluorinated pentahapto η5-C5F5 ring. As a result, the metallapentafluorobenzene isomers are the lowest-energy structures for all three metals.

中文翻译:

环全氟化时,金属茂苯相对于茂金属的相对稳定性增强:镍,钯和铂体系

一个η的全氟化5 -C 5 H ^ 5在MC环10 ħ 10系统(M =镍,钯,铂),得到MC 10 ħ 5 ˚F 5系统大大不稳定含有全氟化pentahaptoη结构5 -C 5 ˚F 5环。结果,金属五氟苯异构体是所有三种金属的最低能级结构。
更新日期:2017-10-16
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