Enhanced Relative Stability of Metallabenzenes versus Metallocenes upon Ring Perfluorination: Nickel, Palladium, and Platinum Systems,European Journal of Inorganic Chemistry

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Enhanced Relative Stability of Metallabenzenes versus Metallocenes upon Ring Perfluorination: Nickel, Palladium, and Platinum Systems
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-10-16 08:20:38 , DOI: 10.1002/ejic.201700810
Jing Li ₁ , Guoliang Li _{1,

2,

3} , Yaoming Xie ₃ , R. Bruce King _{1,

3} , Henry F. Schaefer ₃

Affiliation

Perfluorination of one η⁵-C₅H₅ ring in the MC₁₀H₁₀ system (M = Ni, Pd, Pt) to give an MC₁₀H₅F₅ system greatly destabilizes structures containing a perfluorinated pentahapto η⁵-C₅F₅ ring. As a result, the metallapentafluorobenzene isomers are the lowest-energy structures for all three metals.

中文翻译：

环全氟化时，金属茂苯相对于茂金属的相对稳定性增强：镍，钯和铂体系

一个η的全氟化⁵ -C ₅ H ^ ₅在MC环₁₀ ħ ₁₀系统（M =镍，钯，铂），得到MC ₁₀ ħ ₅ ˚F ₅系统大大不稳定含有全氟化pentahaptoη结构⁵ -C ₅ ˚F ₅环。结果，金属五氟苯异构体是所有三种金属的最低能级结构。

更新日期：2017-10-16

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