Metal-Involving Synthesis and Reactions of Oximes,Chemical Reviews

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Metal-Involving Synthesis and Reactions of Oximes
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-10-09 00:00:00 , DOI: 10.1021/acs.chemrev.7b00264
Dmitrii S. Bolotin ₁ , Nadezhda A. Bokach ₁ , Marina Ya. Demakova ₁ , Vadim Yu. Kukushkin ₁

Affiliation

This review classifies and summarizes the past 10–15 years of advancements in the field of metal-involving (i.e., metal-mediated and metal-catalyzed) reactions of oximes. These reactions are diverse in nature and have been employed for syntheses of oxime-based metal complexes and cage-compounds, oxime functionalizations, and the preparation of new classes of organic species, in particular, a wide variety of heterocyclic systems spanning small 3-membered ring systems to macroheterocycles. This consideration gives a general outlook of reaction routes, mechanisms, and driving forces and underlines the potential of metal-involving conversions of oxime species for application in various fields of chemistry and draws attention to the emerging putative targets.

中文翻译：

涉及金属的肟的合成及反应

这篇综述对肟在涉及金属（即金属介导和金属催化）反应领域中的过去10-15年的进展进行了分类和总结。这些反应的性质各不相同，已用于合成肟基金属配合物和笼型化合物，肟官能化以及制备新型有机物，特别是跨越三元小分子的多种杂环系统环系统到大杂环。这种考虑提供了反应途径，机理和驱动力的总体前景，并强调了涉及肟的金属转化产物在各种化学领域中的应用潜力，并提请人们注意新兴的假定目标。

更新日期：2017-10-09

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