Hydrosulfonylation Reaction with Arenesulfonyl Chlorides and Tetrahydrofuran: Conversion of Terminal Alkynes into Cyclopentylmethyl Sulfones,Angewandte Chemie International Edition

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Hydrosulfonylation Reaction with Arenesulfonyl Chlorides and Tetrahydrofuran: Conversion of Terminal Alkynes into Cyclopentylmethyl Sulfones
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-09-25 11:13:51 , DOI: 10.1002/anie.201707791
Christian Simon Gloor ₁ , Fabrice Dénès ₂ , Philippe Renaud ₁

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A solvent with style: A radical chain reaction was developed for the conversion of terminal alkynes into arenesulfonylmethylcyclopentanes. The radical addition–translocation–cyclization process simply requires the use of arenesulfonyl chlorides in tetrahydrofuran and provides products with a high level of retention of configuration (see scheme).

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