An Extensive Family of Heterometallic Titanium(IV)–Metal(III) Rings with Structure Control through Templates,Angewandte Chemie International Edition

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An Extensive Family of Heterometallic Titanium(IV)–Metal(III) Rings with Structure Control through Templates
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-09-22 06:05:38 , DOI: 10.1002/anie.201706679
Grigore A. Timco ₁ , Antonio Fernandez ₁ , Andreas K. Kostopoulos ₁ , Christopher A. Muryn ₁ , Robin G. Pritchard ₁ , Ilya Strashnov ₁ , Inigo J. Vitorica-Yrezebal ₁ , George F. S. Whitehead ₁ , Richard E. P. Winpenny ₁

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Size control: A family of heterometallic [Cat][Ti_xMO_(x+1)(O₂C ^tBu)_2x+2] rings is reported where Cat=a secondary or tertiary alkyl ammonium ion, x=7, 8 or 9, and M=Fe, Ga, Cr, In and Al. The structures are regular polygons with eight, nine or ten vertices with each edge bridged by an oxide and two pivalates. The size of the ring formed is controlled by the alkylammonium cation present.

中文翻译：

广泛的杂金属钛（IV）-金属（III）环家族，可通过模板进行结构控制

尺寸控制：报告了一个杂金属[Cat] [Ti _x MO _{（x +1}）（O ₂ C ^t Bu）_{2 x +2} ]环，其中Cat =仲或叔烷基铵离子，x = 7，8或9，并且M ＝ Fe，Ga，Cr，In和Al。结构是具有八个，九个或十个顶点的规则多边形，每个边缘由氧化物和两个新戊酸酯桥接。形成的环的大小由存在的烷基铵阳离子控制。

更新日期：2017-09-23

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