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Complexes of {W6I8}4+ Clusters with Carboxylates: Preparation, Electrochemistry, and Luminescence
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-22 05:01:04 , DOI: 10.1002/ejic.201700618 Maxim N. Sokolov 1, 2 , Konstantin A. Brylev 1, 2 , Pavel A. Abramov 1, 2 , Marsel R. Gallyamov 1 , Igor N. Novozhilov 1 , N. Kitamura 3 , Maxim A. Mikhaylov 1
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2017-09-22 05:01:04 , DOI: 10.1002/ejic.201700618 Maxim N. Sokolov 1, 2 , Konstantin A. Brylev 1, 2 , Pavel A. Abramov 1, 2 , Marsel R. Gallyamov 1 , Igor N. Novozhilov 1 , N. Kitamura 3 , Maxim A. Mikhaylov 1
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Octahedral hexatungsten(II) iodide clusters [{W6I8}L8]2– with a series of terminal aliphatic or aromatic carboxylate ligands are prepared. All of the complexes exhibit bright and long-lived emission in CH3CN with quantum yields and lifetimes of 0.39–0.54 and 20.3–42.2 µs, respectively. The redox, spectroscopic, and photophysical properties of [{Mo6I8}L6]2– are modulated by the pKa value of RCOOH.
中文翻译：
{W6I8} 4+簇与羧酸盐的配合物：制备，电化学和发光
制备了具有一系列末端脂族或芳族羧酸酯配体的八面体六钨（II）碘化物簇[{W 6 I 8 } L 8 ] 2-。所有这些配合物在CH 3 CN中均显示出明亮且长寿命的发射，其量子产率和寿命分别为0.39–0.54和20.3–42.2 µs。[{Mo 6 I 8 } L 6 ] 2–的氧化还原，光谱和光物理性质受RCOOH的p K a值调节。
更新日期：2017-09-22
中文翻译：
{W6I8} 4+簇与羧酸盐的配合物：制备，电化学和发光
制备了具有一系列末端脂族或芳族羧酸酯配体的八面体六钨（II）碘化物簇[{W 6 I 8 } L 8 ] 2-。所有这些配合物在CH 3 CN中均显示出明亮且长寿命的发射，其量子产率和寿命分别为0.39–0.54和20.3–42.2 µs。[{Mo 6 I 8 } L 6 ] 2–的氧化还原，光谱和光物理性质受RCOOH的p K a值调节。
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