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A high tenacity electrode by assembly of a soft sorbent and a hard skeleton for lithium–sulfur batteries
Journal of Materials Chemistry A ( IF 10.7 ) Pub Date : 2017-09-04 00:00:00 , DOI: 10.1039/c7ta07063b
Xiaonan Tang 1, 2, 3, 4, 5 , Zhenhua Sun 4, 5, 6, 7, 8 , Ji Liang 4, 5, 6, 7, 8 , Jinping Zhao 1, 2, 3, 4 , Hui-Ming Cheng 4, 5, 6, 7, 8 , Shuping Zhuo 1, 2, 3, 4 , Feng Li 4, 5, 6, 7, 8
Affiliation  

The volume expansion of a sulfur cathode can be accommodated by fabricating a composite structure with a soft (nitrogen-doped graphene) and a hard (silicon carbide whisker) material in lithium sulfur batteries. Due to trapping of soluble polysulfides by soft nitrogen-doped graphene and building a strong structure with a hard silicon carbide whisker, it delivered a high specific capacity of 1288 mA h g−1 at a current density of 335 mA g−1 and exhibited a capacity retention of more than 80% after 150 cycles.

中文翻译:

高强度电极,由软吸附剂和硬质骨架组装而成,用于锂硫电池

通过在锂硫电池中制造具有软质材料(掺氮石墨烯)和硬质材料(碳化硅晶须)的复合结构,可以容纳硫阴极的体积膨胀。由于通过软氮掺杂石墨烯捕获了可溶性多硫化物,并用硬质碳化硅晶须建立了牢固的结构,因此它在335 mA g -1的电流密度下提供了1288 mA hg -1的高比容量,并表现出容量150次循环后保留率超过80%。
更新日期:2017-09-22
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