Tuneable nature of metal organic frameworks as heterogeneous solid catalysts for alcohol oxidation,Chemical Communications

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Tuneable nature of metal organic frameworks as heterogeneous solid catalysts for alcohol oxidation
Chemical Communications ( IF 4.3 ) Pub Date : 2017-09-12 00:00:00 , DOI: 10.1039/c7cc05927b
Amarajothi Dhakshinamoorthy _{1,

2,

3} , Abdullah M. Asiri _{4,

5,

6,

7} , Hermenegildo Garcia _{4,

5,

6,

7,

8}

Affiliation

Selective benzyl alcohol oxidation (BA) to benzaldehyde has been frequently used as a benchmark reaction to evaluate the catalytic activity of metal organic frameworks (MOFs) as oxidation catalysts. Substituted BAs, and aliphatic and allylic alcohols have also been often used as substrates in these studies. In the present review, the current state of the art of MOFs as heterogeneous catalysts for the oxidation of BA and other alcohols is described, grouping the reports according to the nature of the active sites present on the MOFs. Thus, MOFs in which the catalytic centres are located at the ligands, at metallic nodes, or at metal nanoparticles (MNPs) incorporated within the MOF pores and photoassisted oxidations have been commented on. The aim of this review is to stress the current limitations encountered in the use of MOFs, particularly with respect to MOF stability and activity and propose new targets in the area.

中文翻译：

金属有机骨架作为乙醇氧化的非均相固体催化剂的可调性

选择性苯甲醇氧化为苯甲醛的方法经常被用作基准反应，以评估金属有机骨架（MOF）作为氧化催化剂的催化活性。在这些研究中，取代的BA，脂肪族和烯丙基醇也经常被用作底物。在本综述中，描述了MOF作为BA和其他醇氧化的非均相催化剂的最新技术水平，并根据MOF上存在的活性位点的性质对报告进行了分组。因此，已经评论了其中催化中心位于配体，金属节点或结合在MOF孔中的金属纳米颗粒（MNP）和光辅助氧化的MOF。这次审查的目的是强调在使用MOF时遇到的当前限制，

更新日期：2017-09-22

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