Selective and Efficient Iridium Catalyst for the Reductive Amination of Levulinic Acid into Pyrrolidones,ChemSusChem

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Selective and Efficient Iridium Catalyst for the Reductive Amination of Levulinic Acid into Pyrrolidones
ChemSusChem ( IF 7.5 ) Pub Date : 2017-09-21 07:50:52 , DOI: 10.1002/cssc.201701299
Shengdong Wang ₁ , Haiyun Huang ₁ , Christian Bruneau ₁ , Cédric Fischmeister ₁

Affiliation

Ooh LA LA: The reductive amination of levulinic acid with a variety of aliphatic amines and aniline derivatives including sterically hindered amines is presented. The reaction is promoted by an iridium catalyst operating at low loading and 5 bar H₂ under neat conditions. The catalyst was also efficient for the synthesis of N-aryl isoindolinone in high yields.

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