Decoration of exfoliated black phosphorus with nickel nanoparticles and its application in catalysis,Chemical Communications

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Decoration of exfoliated black phosphorus with nickel nanoparticles and its application in catalysis
Chemical Communications ( IF 4.3 ) Pub Date : 2017-09-21 00:00:00 , DOI: 10.1039/c7cc05906j
Maria Caporali _{1,

2,

3} , Manuel Serrano-Ruiz _{1,

2,

3} , Francesca Telesio _{3,

4,

5,

6} , Stefan Heun _{3,

4,

5,

6} , Giuseppe Nicotra _{3,

7,

8,

9} , Corrado Spinella _{3,

7,

8,

9} , Maurizio Peruzzini _{1,

2,

3}

Affiliation

Nickel nanoparticles were dispersed on the surface of exfoliated black phosphorus and the resulting nanohybrid Ni/2DBP showed an improved stability with respect to pristine 2D BP when kept under ambient conditions in the dark. Ni/2DBP was applied as a catalyst in the semihydrogenation of phenylacetylene and exhibited high conversion and selectivity towards styrene. These features were preserved after recycling tests revealing the high stability of the nanohybrid.

中文翻译：

镍纳米粒子修饰脱落的黑磷及其在催化中的应用

镍纳米颗粒分散在剥落的黑磷表面上，所得的纳米混合Ni / 2DBP在黑暗中于环境条件下显示出相对于原始2D BP更高的稳定性。Ni / 2DBP在苯乙炔的半氢化反应中用作催化剂，并显示出高转化率和对苯乙烯的选择性。循环测试表明纳米杂化物的高稳定性后，这些特征得以保留。

更新日期：2017-09-21

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