Boron–Heteroatom Addition Reactions via Borylative Heterocyclization: Oxyboration, Aminoboration, and Thioboration,Accounts of Chemical Research

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Boron–Heteroatom Addition Reactions via Borylative Heterocyclization: Oxyboration, Aminoboration, and Thioboration
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2017-09-21 00:00:00 , DOI: 10.1021/acs.accounts.7b00365
Adena Issaian ₁ , Kim N. Tu ₁ , Suzanne A. Blum ₁

Affiliation

Organoboron compounds and heterocycles are powerful building blocks and precursors for organic synthesis, including for drug discovery and agrochemical and material synthesis. The common strategy for the synthesis of borylated heterocycles involves two separate synthetic steps: first, synthesis of the heterocyclic core, and second, borylation of the core through established methods such as transition-metal-catalyzed C–H or C–X activation/borylation or lithiation/borylation.

中文翻译：

通过硼化杂环的硼-杂原子加成反应：氧硼化，氨基硼化和硫代硼化

有机硼化合物和杂环化合物是有机合成（包括用于药物发现以及农业化学和材料合成）的强大构建基块和前体。合成硼化杂环的通用策略涉及两个单独的合成步骤：首先，合成杂环核，其次，通过已建立的方法（例如过渡金属催化的C–H或C–X活化/硼化）使核心硼化或锂化/硼化。

更新日期：2017-09-21

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