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Recent Developments in Palladium-Catalyzed Oxidative Cascade Carbocyclization
ACS Catalysis ( IF 11.3 ) Pub Date : 2017-09-21 00:00:00 , DOI: 10.1021/acscatal.7b02438
Di Zhang 1 , Jianguo Liu 2 , Armando Córdova 2, 3 , Wei-Wei Liao 1
Affiliation  

In this Perspective, we describe recent advances on Pd-catalyzed oxidative cascade carbocyclizations. These cascade processes enable efficient construction of the molecular complexity and structural diversity of carbocyclic compounds via introducing diverse functionalities concomitant with multiple C–C bond-formations in one-pot operations. In many cases, these processes are facilitated by Pd-catalysts alone, while cocatalysis by combination of Pd catalyst and other catalysts are also discussed, since they represent a new entry to address the preparation of functionalized cyclic compounds with high efficiency and selectivity.

中文翻译:

钯催化氧化级联碳环化的最新进展

在此观点中,我们描述了Pd催化的氧化级联碳环化反应的最新进展。这些级联过程可通过一锅操作引入多种官能团并伴随多个C–C键形成,从而有效构建碳环化合物的分子复杂性和结构多样性。在许多情况下,这些方法仅靠Pd催化剂就可以促进,同时还讨论了通过Pd催化剂与其他催化剂的组合进行的共催化,因为它们代表了一种新的切入点,可以高效且选择性地制备官能化的环状化合物。
更新日期:2017-09-21
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