Catalytic Carbonylative Rearrangement of Norbornadiene via Dinuclear Carbon–Carbon Oxidative Addition,Journal of the American Chemical Society

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Catalytic Carbonylative Rearrangement of Norbornadiene via Dinuclear Carbon–Carbon Oxidative Addition
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2017-09-21 00:00:00 , DOI: 10.1021/jacs.7b08691
Douglas R. Hartline ₁ , Matthias Zeller ₁ , Christopher Uyeda ₁

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Single bonds between carbon atoms are inherently challenging to activate using transition metals; however, ring-strain release can provide the necessary thermodynamic driving force to make such processes favorable. In this report, we describe a strain-induced C–C oxidative addition of norbornadiene. The reaction is mediated by a dinuclear Ni complex, which also serves as a catalyst for the carbonylative rearrangement of norbornadiene to form a bicyclo[3.3.0] product.

中文翻译：

双核碳-碳氧化加成反应降冰片二烯的催化羰基化重排

碳原子之间的单键天生具有挑战性，需要使用过渡金属进行活化。然而，释放环应变可以提供必要的热力学驱动力，以使这种过程变得有利。在本报告中，我们描述了降冰片二烯的应变诱导的C–C氧化加成。该反应由双核镍配合物介导，该配合物还用作降冰片二烯羰基化重排形成双环[3.3.0]产物的催化剂。

更新日期：2017-09-21

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