Syndiotactic polystyrene (SPS) has a unique crystalline phase, named ε, that has a tubular cavity inside. We connected these cavities by optimizing the solvent used to process the films and to polymerize aniline within these channeling cavities only by immersing the films in degassed hydrochloric acid solutions of ammonium persulfate. We succeeded in fixing pentameric to octameric oligoaniline in the cavities of the SPS ε crystalline phase. This is a new and sophisticated preparation method of polymer composites between SPS and linear oligomers/polymers within its long-connected tubular cavities.

中文翻译：

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苯胺在间规聚苯乙烯晶相管腔中的聚合：一种复杂聚合物复合材料的制备方法的建议

间规聚苯乙烯 (SPS) 有一个独特的结晶相，称为 ε，其内部有一个管状空腔。我们通过优化用于处理薄膜的溶剂来连接这些空腔，并且仅通过将薄膜浸入过硫酸铵的脱气盐酸溶液中来在这些通道空腔​​内聚合苯胺。我们成功地将五聚体到八聚体低聚苯胺固定在 SPS ε 结晶相的空腔中。这是在其长连接的管状腔内制备 SPS 和线性低聚物/聚合物之间的聚合物复合材料的一种新的、复杂的制备方法。