Probing RbBr solvation in freestanding sub-2 nm water clusters,Physical Chemistry Chemical Physics

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Probing RbBr solvation in freestanding sub-2 nm water clusters
Physical Chemistry Chemical Physics ( IF 2.9 ) Pub Date : 2017-09-04 00:00:00 , DOI: 10.1039/c7cp04398h
Lauri Hautala _{1,

2,

3,

4} , Kari Jänkälä _{1,

2,

3,

4} , Mikko-Heikki Mikkelä _{5,

6,

7,

8} , Paavo Turunen _{1,

2,

3,

4} , Nønne L. Prisle _{1,

2,

3,

4} , Minna Patanen _{1,

2,

3,

4} , Maxim Tchaplyguine _{5,

6,

7,

8} , Marko Huttula _{1,

2,

3,

4}

Affiliation

Concentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg⁻¹. For comparison, spectra from anhydrous RbBr clusters are also presented.

中文翻译：

在独立的亚2 nm水簇中探测RbBr溶剂化

使用同步加速器辐射的核心能级光电子能谱研究了独立的亚2 nm水簇中RbBr的浓度依赖性溶剂化。从稀簇到饱和簇记录的光谱特征表明，当浓度超过2 mol kg ^-1时，溶剂共享或接触离子对的存在量都会增加。为了进行比较，还给出了无水RbBr团簇的光谱。

更新日期：2017-09-20

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