In many industrial applications, (CF₃)₂CFCN has been suggested as SF₆ substitute, which possess a global warming potential (GWP₁₀₀-yr) of 23500 relative to CO₂. The temperature dependence of the rate coefficient (k_OH) for the OH+(CF₃)₂CFCN reaction is reported for the first time: k_OH(278–358 K)=(5.9±3.2)×10^-13exp{-(1856±162)/T} cm³ molecule^-1 s^-1. A lifetime of 47 years was estimated relative to that of CH₃CCl₃. Infrared absorption cross sections were also determined to derive the radiative efficiency (0.28 W m^-2 ppbv^-1). A GWP₁₀₀-yr of 3646 was estimated, resulting in a significant reduction of the contribution to global warming if SF₆ was replaced by (CF₃)₂CFCN.

中文翻译：

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（CF ₃）₂ CFCN与OH自由基的反应动力学随温度（278-358 K）的变化：温室SF _6的良好替代品？

在许多工业应用中，已经提出了（CF ₃）₂ CFCN作为SF _6的替代物，它具有相对于CO ₂的23500的全球变暖潜能（GWP ₁₀₀年）。首次报道了OH +（CF ₃）₂ CFCN反应的速率系数（k _OH）与温度的关系：k _OH（278–358 K）=（5.9±3.2）×10 ^-13 exp {-（ 1856±162）/ T } cm ³分子^-1 s ^-1。相对于CH ₃ CCl ₃，估计寿命为47年。。还确定了红外吸收截面，以得出辐射效率（0.28 W m ^-2 ppbv ^-1）。据估计，全球升温潜能值为₁₀₀年的3646年，如果用（CF ₃）₂ CFCN代替SF ₆，将大大降低对全球变暖的贡献。