Long-range magnetic ordering in a metal–organic framework based on octanuclear nickel(II) clusters,Dalton Transactions

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Long-range magnetic ordering in a metal–organic framework based on octanuclear nickel(II) clusters
Dalton Transactions ( IF 3.5 ) Pub Date : 2017-09-06 00:00:00 , DOI: 10.1039/c7dt02889j
Jun-Li Wang _{1,

2,

3,

4,

5} , Yan Bai _{1,

2,

3,

4,

5} , Hui Pan _{1,

2,

3,

4,

5} , Guang-Shui Zheng _{1,

2,

3,

4,

5} , Dong-Bin Dang _{1,

2,

3,

4,

5}

Affiliation

A novel three-dimensional metal–organic framework [Ni₃(BTC)₂(bpp)₂(H₂O)]·3H₂O (1) based on mixed ligands H₃BTC (1,2,4-benzenetricarboxylic acid) and bpp (1,3-bis(4-pyridyl)propane) was obtained under hydrothermal conditions. Crystal structure analysis reveals that 1 is a framework based on cage-like Ni₈(COO)₁₂ units. Furthermore, long-range magnetic ordering is observed at low temperature.

中文翻译：

基于八核镍（II）团簇的金属有机框架中的远距离磁有序

基于混合配体H ₃ BTC（1,2,4-苯三甲酸）的新型三维金属有机骨架[Ni ₃（BTC）₂（bpp）₂（H ₂ O）]·3H ₂ O（1）在水热条件下得到bpp（1，3-双（4-吡啶基）丙烷）。晶体结构分析表明1是基于笼状Ni ₈（COO）₁₂单元的骨架。此外，在低温下观察到远距离磁排序。

更新日期：2017-09-20

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