Ring expansion of a ring expanded carbene,Dalton Transactions

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Ring expansion of a ring expanded carbene
Dalton Transactions ( IF 4 ) Pub Date : 2017-08-21 00:00:00 , DOI: 10.1039/c7dt03046k
Lucía García _{1,

2,

3,

4} , Khalidah H. M. Al Furaiji _{5,

6,

7,

8,

9} , David J. D. Wilson _{5,

6,

7,

8,

9} , Jason L. Dutton _{5,

6,

7,

8,

9} , Michael S. Hill _{1,

2,

3,

4} , Mary F. Mahon _{1,

2,

3,

4}

Affiliation

Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si–H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si–H or Si–Ph bonds.

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