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Single-crystal UV-vis spectroscopic examination of a striking odd–even effect on structure and chromic behaviour of salicylidene alkylamines
Chemical Communications ( IF 4.3 ) Pub Date : 2017-09-14 00:00:00 , DOI: 10.1039/c7cc06268k
Hirohiko Houjou 1, 2, 3, 4, 5 , Hana Ikedo 1, 2, 3, 4, 5 , Isao Yoshikawa 1, 2, 3, 4, 5
Affiliation  

We have found that a series of N-(5-bromosalicylidene) alkylamines exhibited distinct chromic behaviour depending on the parity of their alkyl chain length. A group with an even number of carbon atoms in the alkyl chain showed photochromism, while another group with odd number showed thermochromism.

中文翻译:

单晶紫外可见光谱检查对水杨基亚烷基胺的结构和铬行为的显着奇偶影响

我们已经发现,一系列的N-(5-溴水杨基)烷基胺根据其烷基链长度的奇偶性表现出不同的铬行为。烷基链中碳原子数为偶数的基团显示光致变色,而奇数的另一基团显示为热致变色。
更新日期:2017-09-19
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