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Fluorescent photochromic donor-acceptor Stenhouse adduct controlled by visible light
Dyes and Pigments ( IF 4.1 ) Pub Date : 2017-09-19 , DOI: 10.1016/j.dyepig.2017.09.040
Shun Yang , Jing Liu , Zhanqi Cao , Mingming Li , Qianfu Luo , Dahui Qu

A novel photochromic fluorescent DASA (donor-acceptor Stenhouse adduct) switch controlled by visible light was successfully designed and synthesized. Using 1,8-naphthalimide fluorophore in combination with indoline-based “donor” and barbituric acid “acceptor”, the DASA molecule exhibits two independent absorption bands at 440 nm and 616 nm. The physical and thermodynamic properties of fluorescent donor-acceptor Stenhouse adduct (DASA-NDI) have been investigated in different solvents. In accordance with the unique fluorescent properties under visible light/heat and H+/Cu2+, using fluorescence intensity at 604 nm (I604) as an output and visible light, H+ and Cu2+ as inputs, a combinatorial logic gate consisting of NOR and AND logics can be described and operated.



中文翻译:

可见光控制的荧光光致变色供体-Stenhouse加合物

成功设计并合成了一种新型的可见光控制的光致变色荧光DASA(供体-受体Stenhouse加合物)开关。通过结合使用1,8-萘二甲酰亚胺荧光团和基于二氢吲哚的“供体”和巴比妥酸“受体”,DASA分子在440 nm和616 nm处显示两个独立的吸收带。已经在不同溶剂中研究了荧光供体-受体Stenhouse加合物(DASA-NDI 的物理和热力学性质。根据在可见光/热和H + / Cu 2+下的独特荧光特性,使用604 nm(I 604)的荧光强度作为输出以及可见光H +和Cu 2+ 作为输入,可以描述和操作由NOR和AND逻辑组成的组合逻辑门。

更新日期:2017-09-19
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