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The Role of N-Substituents in Radiationless Deactivation of Aminated Derivatives of a Locked GFP Chromophore
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2017-09-19 06:11:35 , DOI: 10.1002/ejoc.201700805 Nadezhda S. Baleeva 1 , Snezhana O. Zaitseva 1 , Dmitriy A. Gorbachev 1 , Alexander Yu. Smirnov 1 , Marina B. Zagudaylova 1 , Mikhail S. Baranov 1
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2017-09-19 06:11:35 , DOI: 10.1002/ejoc.201700805 Nadezhda S. Baleeva 1 , Snezhana O. Zaitseva 1 , Dmitriy A. Gorbachev 1 , Alexander Yu. Smirnov 1 , Marina B. Zagudaylova 1 , Mikhail S. Baranov 1
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Fluorescent dyes based on aminated derivatives of locked GFP chromophores have been developed. Their properties indicate that the fluorescence quantum yield variation is determined by the formation of the nonfluorescent internal charge transfer exited state with a planar quinoidal structure. Thus, the electronic effects have a greater impact on the radiationless deactivation than conformation.
中文翻译：
N-取代基在锁定的GFP发色团的胺化衍生物的无辐射失活中的作用
已经开发了基于锁定的GFP发色团的胺化衍生物的荧光染料。它们的性质表明，荧光量子产率的变化取决于具有平面五面体结构的非荧光内部电荷转移出射态的形成。因此，电子效应对无辐射失活的影响大于构象。
更新日期：2017-09-19
中文翻译：
N-取代基在锁定的GFP发色团的胺化衍生物的无辐射失活中的作用
已经开发了基于锁定的GFP发色团的胺化衍生物的荧光染料。它们的性质表明，荧光量子产率的变化取决于具有平面五面体结构的非荧光内部电荷转移出射态的形成。因此，电子效应对无辐射失活的影响大于构象。
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