The Manganese-Catalyzed Cross-Coupling Reaction and the Influence of Trace Metals,European Journal of Organic Chemistry

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The Manganese-Catalyzed Cross-Coupling Reaction and the Influence of Trace Metals
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2017-09-19 07:05:25 , DOI: 10.1002/ejoc.201701005
Carola Santilli ₁ , Somayyeh Sarvi Beigbaghlou _{1,

2} , Andreas Ahlburg ₁ , Giuseppe Antonacci ₁ , Peter Fristrup ₁ , Per-Ola Norrby _{3,

4} , Robert Madsen ₁

Affiliation

The substrate scope of the MnCl₂-catalyzed coupling between aryl halides and Grignard reagents has been extended to unactivated halides by performing the reaction in a microwave oven. Two previously published cross-coupling reactions with manganese catalysts were revisited and found impossible to reproduce without the assistance of small amounts of palladium or copper.

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