Protonation of Ferrocene: A Low-Temperature X-ray Diffraction Study of [Cp2FeH](PF6) Reveals an Iron-Bound Hydrido Ligand,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Protonation of Ferrocene: A Low-Temperature X-ray Diffraction Study of [Cp2FeH](PF6) Reveals an Iron-Bound Hydrido Ligand
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-09-19 07:46:23 , DOI: 10.1002/anie.201704854
Moritz Malischewski ₁ , Konrad Seppelt ₁ , Jörg Sutter ₂ , Frank W. Heinemann ₂ , Birger Dittrich ₃ , Karsten Meyer ₂

Affiliation

After more than 50 years, the mechanism of electrophilic substitutions on ferrocene was reinvestigated for the simplest electrophile, H⁺, and the potential intermediate [Cp₂FeH]⁺ was isolated. Single crystals of [Cp₂FeH](PF₆) were obtained from an anhydrous HF/PF₅ system. X-ray diffraction analysis revealed a non-agostic structure with an iron-bound hydrido ligand.

中文翻译：

二茂铁的质子化：[Cp2FeH]（PF6）的低温X射线衍射研究揭示了铁结合氢配体

50多年来，重新研究了最简单的亲电子试剂H ^+的二茂铁亲电取代机理，并分离出了潜在的中间体[Cp ₂ FeH] ⁺。从无水HF / PF ₅系统获得[Cp ₂ FeH]（PF ₆）的单晶。X射线衍射分析显示具有铁结合的氢配体的非声波结构。

更新日期：2017-09-19

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11