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Highly Active N,O Zinc Guanidine Catalysts for the Ring-Opening Polymerization of Lactide
ChemSusChem ( IF 7.5 ) Pub Date : 2017-09-19 04:01:11 , DOI: 10.1002/cssc.201701237
Pascal M. Schäfer 1 , Martin Fuchs 1 , Andreas Ohligschläger 2 , Ruth Rittinghaus 1 , Paul McKeown 3 , Enver Akin 4 , Maximilian Schmidt 1 , Alexander Hoffmann 1 , Marcel A. Liauw 2 , Matthew D. Jones 3 , Sonja Herres-Pawlis 1
Affiliation  

Fast and robust! Four fast robust ring-opening polymerization (ROP) catalysts polymerize lactide in high yields and good molar masses with potential for industrial application. All four complexes combine robustness against impurities in the lactide with high polymerization rates, and they represent the fastest robust lactide ROP catalysts to date. End-group analysis was performed to clarify the mechanism.

中文翻译:

丙交酯开环聚合的高活性N,O锌胍催化剂

快速而强大!四种快速耐用的开环聚合(ROP)催化剂以高收率和良好的摩尔质量聚合丙交酯,具有工业应用潜力。所有四种配合物都结合了对丙交酯中杂质的耐受性和高聚合速率,它们代表了迄今为止最快的丙交酯ROP催化剂。进行了端基分析以阐明机理。
更新日期:2017-09-19
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