Highly Active N,O Zinc Guanidine Catalysts for the Ring-Opening Polymerization of Lactide,ChemSusChem

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Highly Active N,O Zinc Guanidine Catalysts for the Ring-Opening Polymerization of Lactide
ChemSusChem ( IF 7.5 ) Pub Date : 2017-09-19 04:01:11 , DOI: 10.1002/cssc.201701237
Pascal M. Schäfer ₁ , Martin Fuchs ₁ , Andreas Ohligschläger ₂ , Ruth Rittinghaus ₁ , Paul McKeown ₃ , Enver Akin ₄ , Maximilian Schmidt ₁ , Alexander Hoffmann ₁ , Marcel A. Liauw ₂ , Matthew D. Jones ₃ , Sonja Herres-Pawlis ₁

Affiliation

Fast and robust! Four fast robust ring-opening polymerization (ROP) catalysts polymerize lactide in high yields and good molar masses with potential for industrial application. All four complexes combine robustness against impurities in the lactide with high polymerization rates, and they represent the fastest robust lactide ROP catalysts to date. End-group analysis was performed to clarify the mechanism.

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