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Simultaneous production of CH4-rich syngas and high-quality tar from lignite by the coupling of noncatalytic/catalytic pyrolysis and gasification in a pressurized integrated fluidized bed
Applied Energy ( IF 11.2 ) Pub Date : 2017-09-18 , DOI: 10.1016/j.apenergy.2017.08.227
Zhaohui Chen , Shiqiu Gao , Guangwen Xu

An integrated fluidized bed (IFB) reactor with a two-stage configuration has been developed to process small-size coal particles for the simultaneous production of CH4-rich syngas and high-quality tar, in which coal pyrolysis occurred in an upper transport bed (TB) within an atmosphere mixing steam and syngas generated by steam-oxygen gasification of coal or char in a lower fluidized bed (FB). The coupling effect was investigated by combining non-catalytic/catalytic pyrolysis and gasification in a pressurized IFB. Having TB pyrolysis obviously raised CH4 yield (also its content in producer gas) and tar yield. The respective contributions to CH4 formation from the TB pyrolysis and FB gasification were mainly relevant to operating pressure and Ca(OH)2 catalyst. Raising pressure facilitated CH4 formation. When lignite was treated without catalyst, the contribution from TB pyrolysis was greater than that from FB gasification as hydropyrolysis was intensified by pressure in H2-rich gas atmosphere from the FB gasifier. Adding catalyst into lignite reversed their contributions. The FB catalytic gasification formed more CH4 because Ca(OH)2 functioned well as a catalyst for CH4 formation in pressurized gasification. With elevated pressure or/and the addition of Ca(OH)2, pyrolysis tar yield decreased in different degrees but its quality was improved. With the combination effect of pressure and Ca(OH)2, producer gas from the tested IFB reactor was highly rich in CH4 to reach 10.8 vol%, with as well a high H2/CO ratio of 2.3 that is suitable for making SNG. The obtained tar had its light tar content as high as 95 wt%.



中文翻译:

通过在加压集成流化床中进行非催化/催化热解和气化的耦合,从褐煤同时生产富含CH 4的合成气和高质量焦油

已开发出具有两阶段配置的集成流化床(IFB)反应器,可处理小尺寸的煤颗粒,以同时生产富含CH 4的合成气和高质量的焦油,其中煤的热解发生在上部运输床中(TB)在大气中混合蒸汽和合成气,这些蒸汽和合成气是通过下部流化床(FB)中的煤或炭的蒸汽-氧气气化而产生的。通过在加压IFB中结合非催化/催化热解和气化研究耦合效应。进行TB热解明显提高了CH 4的收率(也包括其在生产气中的含量)和焦油的收率。TB热解和FB气化对CH 4形成的贡献主要与工作压力和Ca(OH)有关2催化剂。升高压力促进了CH 4的形成。当褐煤在没有催化剂的情况下处理时,TB热解的贡献大于FB气化的贡献,因为通过FB气化器在富含H 2的气体气氛中加氢热解。在褐煤中添加催化剂可逆转其贡献。FB催化气化可形成更多的CH 4,因为Ca(OH)2在加压气化中可作为CH 4形成催化剂。随着压力的升高和/或Ca(OH)2的添加,热解焦油收率有不同程度的下降,但其质量有所提高。结合压力和Ca(OH)2的作用,来自经过测试的IFB反应器的生产气富含CH 4达到10.8 vol%,并且H 2 / CO比率高达2.3,适合于生产SNG。所得焦油的轻焦油含量高达95重量%。

更新日期:2017-09-18
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