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Synthesis and optical properties of P5+ co-doped Ba3SiO5:Eu2+ orange persistent phosphor
Dyes and Pigments ( IF 4.1 ) Pub Date : 2017-09-18 , DOI: 10.1016/j.dyepig.2017.09.038
Seung Hee Choi , Seok Bin Kwon , Usama Bin Humayoun , Won Kyu Park , Kenji Toda , Masato Kakihana , Takaki Masaki , Woo Seok Yang , Young Hyun Song , Dae Ho Yoon

By co-doping the P5+ ions into Ba3SiO5:Eu2+, we synthesized new orange persistent phosphor using cellulose assisted liquid phase precursor (LPP) method. The emission spectra showed a typically broad orange emission band centered at 575 nm attributed to the 4f65d1 → 4f7 transition of Eu2+ ions under 400 nm excitation source. The persistent luminescence property of Eu2+ doped Ba3SiO5 orange phosphor was enhanced by co-doping non-equivalent phosphorus ions into silicon sites. This enhancement can be explained by formation of the trapping center due to the charge compenstation. Consequently, the afterglow decay exhibited an orange emission for more than 5 min after irradiation at under 365 nm for 1 min.



中文翻译:

P 5+共掺杂Ba 3 SiO 5:Eu 2+橙色持久荧光粉的合成及光学性质

通过将P 5+离子共掺杂到Ba 3 SiO 5:Eu 2+中,我们使用纤维素辅助液相前驱体(LPP)方法合成了新的橙色持久性磷光体。发射光谱显示出典型的宽橙色发射带,中心在575 nm处,这归因于在400 nm激发源下Eu 2+离子从4f 6 5d 1 →4f 7跃迁。Eu 2+掺杂Ba 3 SiO 5的持久发光性能通过将非等价的磷离子共掺杂到硅部位来增强橙色荧光粉。这种增强可以通过由于电荷补偿而形成的俘获中心来解释。因此,在365 nm下照射1分钟后,余辉衰减显示出超过5分钟的橙色发射。

更新日期:2017-09-18
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