Switchable synthesis of furfurylamine and tetrahydrofurfurylamine from furfuryl alcohol over RANEY® nickel,Catalysis Science & Technology

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Switchable synthesis of furfurylamine and tetrahydrofurfurylamine from furfuryl alcohol over RANEY® nickel
Catalysis Science & Technology ( IF 4.4 ) Pub Date : 2017-08-17 00:00:00 , DOI: 10.1039/c7cy00981j
Yingxin Liu _{1,

2,

3,

4,

5} , Kuo Zhou _{1,

2,

3,

4,

5} , Huimin Shu _{1,

2,

3,

4,

5} , Haiyan Liu _{1,

2,

3,

4,

5} , Jiongtao Lou _{5,

6,

7,

8,

9} , Dechao Guo _{5,

6,

7,

8,

9} , Zuojun Wei _{5,

6,

7,

8,

9} , Xiaonian Li _{3,

4,

5,

10,

11}

Affiliation

RANEY® Ni proved to be an effective heterogeneous catalyst for switchable reductive amination of furfuryl alcohol to tetrahydrofurfurylamine and furfurylamine with NH₃ by simply adding or not adding 1.0 MPa H₂ into the reaction bulk. After further optimization of the reaction conditions, we finally obtained 94.0% yield of tetrahydrofurfurylamine and 78.8% yield of furfurylamine with high selectivity. By extensively studying the catalytic pathways and mechanism of catalyst deactivation with XRD and XPS characterization, we have confirmed that an excess amount of H₂ in the reaction bulk leads to the deep hydrogenation of the furan ring while an insufficient amount of H₂ leads to the formation of Ni₃N and the deactivation of the catalyst.

中文翻译：

在RANEY®镍上由糠醇可转换合成糠胺和四氢糠胺

通过简单地在反应物料中添加或不添加1.0 MPa H _2，证明RANEY®Ni是一种有效的非均相催化剂，可用于糠醇可转换还原胺化为NH ₃的四氢糠胺和糠胺。在进一步优化反应条件后，我们最终以高选择性获得了94.0％的四氢糠胺和78.8％的糠胺收率。通过广泛研究XRD和XPS表征的催化途径和催化剂失活的机理，我们已经确认，反应主体中过量的H ₂导致呋喃环的深度氢化，而不足量的H ₂导致呋喃环的加氢。Ni _3的形成N和催化剂失活。

更新日期：2017-09-19

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