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Microwave-hydrothermal synthesis of a novel, recyclable and stable photocatalytic nanoreactor for recognition and degradation of tetracycline
Catalysis Science & Technology ( IF 5 ) Pub Date : 2017-08-14 00:00:00 , DOI: 10.1039/c7cy01330b
Zhi Zhu 1, 2, 3, 4 , Yang Yu 1, 2, 3, 4 , Hai Huang 1, 2, 3, 4 , Xin Yao 1, 2, 3, 4 , Hongjun Dong 1, 2, 3, 4 , Zhi Liu 4, 5, 6 , Yongsheng Yan 1, 2, 3, 4 , Chunxiang Li 1, 2, 3, 4 , Pengwei Huo 1, 2, 3, 4
Affiliation  

A unique Ppy@CdS/ZnFe2O4 nanoreactor is fabricated via the microwave-hydrothermal method and surface-imprinting technique, which effectively enhances the recyclability, stability, and selectivity for recognition and degradation of tetracycline under visible-light irradiation. The as-prepared functional nanoreactor enables photocatalytic reactions with little loss of activity during the recycling process. In addition, the capture experiments and ESR exploration show that h+ and ˙OH play the major roles in this photocatalytic reaction. Therefore, this study not only puts forward a novel design concept that develops the potential application value of CdS, but also provides a new approach for inhibiting its secondary pollution. Moreover, this nanoreactor has huge potential for the continuous and selective decomposition of specific pollutant molecules according to practical requirements.

中文翻译:

微波水热合成新颖,可回收且稳定的光催化纳米反应器,用于识别和降解四环素

通过微波水热法和表面压印技术制备了独特的Ppy @ CdS / ZnFe 2 O 4纳米反应器,有效地提高了在可见光照射下四环素的可回收性,稳定性和选择性以及对四环素的识别和降解选择性。所制备的功能性纳米反应器能够进行光催化反应,而在回收过程中活性几乎没有损失。此外,捕获实验和ESR探索表明,h +˙OH在该光催化反应中起主要作用。因此,本研究不仅提出了开发CdS潜在应用价值的新颖设计理念,而且为抑制CdS的二次污染提供了新途径。而且,这种纳米反应器根据实际需要具有对特定污染物分子进行连续和选择性分解的巨大潜力。
更新日期:2017-09-19
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