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B(MIDA)-Containing Diborons
ACS Omega ( IF 4.1 ) Pub Date : 2017-09-18 00:00:00 , DOI: 10.1021/acsomega.7b01042
Hiroto Yoshida 1 , Michinari Seki 1 , Ikuo Kageyuki 1 , Itaru Osaka 1 , Sayaka Hatano 1 , Manabu Abe 1
Affiliation  

Unsymmetrical B(MIDA)-containing diborons of potential synthetic utility were found to be synthesized from the readily available (neop)B–B(neop) and (HO)2B–B(OH)2, and the procedure was extended to the generation of symmetrical (MIDA)B–B(MIDA). NMR and X-ray crystal structure studies revealed that B(MIDA) units of all of the diborons obtained in this study were in rigid tetrahedral environment.

中文翻译:

B(MIDA)-含硼

已发现从容易获得的(neop)B–B(neop)和(HO)2 B–B(OH)2合成了具有潜在合成效用的不对称含B(MIDA)的硼,该程序已扩展至对称(MIDA)B–B(MIDA)的生成。NMR和X射线晶体结构研究表明,本研究中获得的所有二硼烷的B(MIDA)单元均处于刚性四面体环境中。
更新日期:2017-09-18
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