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Dynamic π-Conjugated Polymer Ionic Networks
Macromolecules ( IF 5.1 ) Pub Date : 2017-09-18 00:00:00 , DOI: 10.1021/acs.macromol.7b01896 Shekhar Shinde 1 , Jenna L. Sartucci 1 , Dorothy K. Jones 1 , Nagarjuna Gavvalapalli 1
Macromolecules ( IF 5.1 ) Pub Date : 2017-09-18 00:00:00 , DOI: 10.1021/acs.macromol.7b01896 Shekhar Shinde 1 , Jenna L. Sartucci 1 , Dorothy K. Jones 1 , Nagarjuna Gavvalapalli 1
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The elastic nature of π-conjugated polymer gels makes it difficult to process them using traditional coating techniques and inkjet printing, and as injectable gels, thereby limiting the use of preprocessing and storing the polymers as gels. Taking cues from the easy processability of reversible and thixotropic non-π-conjugated polymer gels, we report herein for the first time a simple strategy to obtain reversible and thixotropic π-conjugated polymer ionic network (π-PIN) gels. Reversible and thixotropic π-PIN gels are generated by synergistically combining the intriguing properties of π-conjugated polymers with the dynamic properties of ionically cross-linked networks.
中文翻译：
动态π共轭聚合物离子网络
π-共轭聚合物凝胶的弹性性质使得难以使用传统的涂布技术和喷墨印刷以及作为可注射凝胶来对其进行加工，从而限制了将聚合物预处理并存储为凝胶的用途。从可逆和触变非π共轭聚合物凝胶的易加工性中获得启示，我们首次在本文中报道了一种简单的策略来获得可逆和触变π共轭聚合物离子网络（π-PIN）凝胶。可逆和触变的π-PIN凝胶是通过将π-共轭聚合物的迷人特性与离子交联网络的动态特性协同结合而产生的。
更新日期：2017-09-18
中文翻译：
动态π共轭聚合物离子网络
π-共轭聚合物凝胶的弹性性质使得难以使用传统的涂布技术和喷墨印刷以及作为可注射凝胶来对其进行加工，从而限制了将聚合物预处理并存储为凝胶的用途。从可逆和触变非π共轭聚合物凝胶的易加工性中获得启示，我们首次在本文中报道了一种简单的策略来获得可逆和触变π共轭聚合物离子网络（π-PIN）凝胶。可逆和触变的π-PIN凝胶是通过将π-共轭聚合物的迷人特性与离子交联网络的动态特性协同结合而产生的。
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