Catalytic Enantioselective Synthesis of Highly Functionalized Difluoromethylated Cyclopropanes,Angewandte Chemie International Edition

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Catalytic Enantioselective Synthesis of Highly Functionalized Difluoromethylated Cyclopropanes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-09-18 11:39:39 , DOI: 10.1002/anie.201707375
Maxence Bos _{1,

2} , Wei-Sheng Huang ₁ , Thomas Poisson ₁ , Xavier Pannecoucke ₁ , André B. Charette ₂ , Philippe Jubault ₁

Affiliation

Small rings: The first catalytic asymmetric synthesis of difluorinated cyclopropanes is described. The methodology employs a rhodium catalyst and affords access to functionalized cyclopropanes in high yields with high diastereo- and enantioselectivities. PMP=para-methoxyphenyl.

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