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Optimizing Optical Absorption, Exciton Dissociation, and Charge Transfer of a Polymeric Carbon Nitride with Ultrahigh Solar Hydrogen Production Activity
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-09-18 11:33:33 , DOI: 10.1002/anie.201706870
Guigang Zhang 1 , Guosheng Li 2 , Zhi-An Lan 2 , Lihua Lin 2 , Aleksandr Savateev 1 , Tobias Heil 1 , Spiros Zafeiratos 3 , Xinchen Wang 2 , Markus Antonietti 1
Affiliation  

Free to dissociate: The simultaneous modification of the electronic band structures, layer-stacking geometry, and crystallinity of carbon nitride polymers enables the liberation of Frenkel exciton dissociation and magnification of the hot-charges yield, which dramatically enhances the visible-light photocatalytic activities.

中文翻译:

优化具有超高太阳产氢活性的聚合碳氮化物的光吸收,激子解离和电荷转移

自由解离:同时改变电子能带结构,层堆叠的几何形状和氮化碳聚合物的结晶度,可以释放Frenkel激子解离并放大热电荷产率,从而显着增强可见光的光催化活性。
更新日期:2017-09-19
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