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Design for a small molecule based chemosensor containing boron and pyridine moieties to detect HF
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2017-09-17 , DOI: 10.1016/j.snb.2017.09.072 Ying Hu , Mahnseok Kye , Ji Young Jung , Yong-beom Lim , Juyoung Yoon
中文翻译:
基于小分子的化学传感器的设计,该化学传感器包含硼和吡啶部分以检测HF
更新日期:2017-09-17
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2017-09-17 , DOI: 10.1016/j.snb.2017.09.072 Ying Hu , Mahnseok Kye , Ji Young Jung , Yong-beom Lim , Juyoung Yoon
A new triarylborane compound 1 is described as fluorescent probe for HF gas with high sensitivity and selectivity. The system utilized the coordination of a fluoride ion to the boron center in 1 to cause perturbation in the energy transfer pathway and the π conjugation, which induced distinct fluorescent quenching. A probe 1-coated film was further applied to detect HF gas via a unique capacitance change.
中文翻译:
基于小分子的化学传感器的设计,该化学传感器包含硼和吡啶部分以检测HF
一种新型的三芳基硼烷化合物1被描述为具有高灵敏度和选择性的HF气体荧光探针。该系统利用氟离子在1中与硼中心的配位来引起能量转移途径的扰动和π共轭,从而引起明显的荧光猝灭。进一步涂覆探针1涂覆的薄膜,以通过独特的电容变化检测HF气体。