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UV–vis and fluorescence detection by receptors based on an isophthalamide bearing a phenylethynyl group
Tetrahedron Letters ( IF 1.8 ) Pub Date : 2017-09-18 , DOI: 10.1016/j.tetlet.2017.09.043
Shin-ichi Kondo , Kimihiro Endo , Jun Iioka , Keisuke Sato , Yuka Matsuta

We have successfully prepared 5-(2-phenylethynyl)isophathalilc acid as a signaling unit and the corresponding derivatives for an anion receptor 2 and a barbiturate receptor 4. Receptor 2 showed characteristic UV–vis changes and dramatic fluorescence quenching upon the addition of anions and receptor 4 showed UV–vis and an OFF-ON fluorescence changes upon the addition of dibutylbarbituric acid based on the diphenylethyne moiety.



中文翻译:

通过带有苯基乙炔基的间苯二甲酰胺受体的紫外可见和荧光检测

我们已经成功地制备了5-(2-苯基乙炔基)异邻苯二酸作为信号传导单元,以及相应的阴离子受体2和巴比妥酸酯受体4的衍生物。受体2表现出特征性的UV-vis变化,加入阴离子后荧光急剧淬灭,受体4表现出UV-vis且基于二苯基乙炔部分添加二丁基巴比妥酸时OFF-ON荧光变化。

更新日期:2017-09-18
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