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Independent macroscopic chemical mappings of cultural heritage materials with reflectance imaging spectroscopy : the case study of a 16th century Aztec manuscript
Analytical Methods ( IF 2.7 ) Pub Date : 2017-09-18 00:00:00 , DOI: 10.1039/c7ay00749c
Fabien Pottier 1, 2, 3, 4, 5 , Salomon Kwimang 1, 2, 3, 4, 5 , Anne Michelin 1, 2, 3, 4, 5 , Christine Andraud 1, 2, 3, 4, 5 , Fabrice Goubard 6, 7, 8, 9 , Bertrand Lavédrine 1, 2, 3, 4, 5
Affiliation  

Reflectance spectral imaging is a powerful tool for the non-invasive study of cultural heritage objects. Particular visible to short wave infrared (400-2500 nm) spectral features are linked to compositional information which, thanks to spectral images, can generate useful chemical maps. However, in the case of complex mixtures, the global shape of the pure materials reflectance spectra is affected by the presence of other absorbing materials. When studying heterogeneous polychromatic surfaces in which the same material is found in different color preparations (hence presenting different global absorption characteristics), this aspect can strongly affect the success of the targeted chemical mappings. As a result, several spectral processing steps are necessary in order to overcome the presence of interfering materials. The case study of the Codex Borbonicus, a precious 16thcentury Aztec manuscript is reported here. Visible and short wave infrared reflectance images of the document were scanned in situ. In order to obtain material specific mappings that are not affected by the presence of pigment mixtures, the necessity of applying particular spectral treatments is shown. The flaws and qualities of the resulting chemical images are discussed, along with their general potential for cultural heritage case studies. Ultimately, the independent macroscopic chemical maps of cochineal lake, gypsum and palygorskite (the clay that composes the mineral matrix of the famous Maya blue pigment) on the pages of the manuscript are successfully obtained.

中文翻译:

具有反射成像光谱学的文化遗产材料的独立宏观化学制图:以16世纪阿兹台克人手稿为例

反射光谱成像是对文化遗产对象进行非侵入式研究的强大工具。特定的可见光到短波红外(400-2500 nm)光谱特征与成分信息相关,由于光谱图像,成分信息可以生成有用的化学图。但是,在复杂混合物的情况下,纯材料反射光谱的整体形状会受到其他吸收材料的影响。在研究异质多色表面时,其中在不同的颜色准备中发现了相同的材料(因此呈现出不同的全局吸收特性),这一方面会极大地影响目标化学图谱的成功。结果,为了克服干扰材料的存在,需要几个光谱处理步骤。此处报道了珍贵的16世纪阿兹台克人手稿《食典委》的案例研究。原位扫描文件的可见光和短波红外反射图像。为了获得不受颜料混合物存在影响的材料特定的映射,显示了应用特定光谱处理的必要性。讨论了所得化学图像的缺陷和质量,以及它们在文化遗产案例研究中的一般潜力。最终,在手稿页面上成功获得了胭脂树湖,石膏和坡缕石(构成著名玛雅人蓝色颜料的矿物基质的粘土)的独立宏观化学图谱。原位扫描文件的可见光和短波红外反射图像。为了获得不受颜料混合物存在影响的材料特定的映射,显示了应用特定光谱处理的必要性。讨论了所得化学图像的缺陷和质量,以及它们在文化遗产案例研究中的一般潜力。最终,在手稿页面上成功获得了胭脂树湖,石膏和坡缕石(构成著名玛雅人蓝色颜料的矿物基质的粘土)的独立宏观化学图谱。原位扫描文件的可见光和短波红外反射图像。为了获得不受颜料混合物存在影响的材料特定的映射,显示了应用特定光谱处理的必要性。讨论了所得化学图像的缺陷和质量,以及它们在文化遗产案例研究中的一般潜力。最终,在手稿页面上成功获得了胭脂树湖,石膏和坡缕石(构成著名玛雅人蓝色颜料的矿物基质的粘土)的独立宏观化学图谱。讨论了所得化学图像的缺陷和质量,以及它们在文化遗产案例研究中的一般潜力。最终,在手稿页面上成功获得了胭脂树湖,石膏和坡缕石(构成著名玛雅人蓝色颜料的矿物基质的粘土)的独立宏观化学图谱。讨论了所得化学图像的缺陷和质量,以及它们在文化遗产案例研究中的一般潜力。最终,在手稿页面上成功获得了胭脂树湖,石膏和坡缕石(构成著名玛雅人蓝色颜料的矿物基质的粘土)的独立宏观化学图谱。
更新日期:2017-09-18
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